Think about your answer, then reveal below.
Model answer: The sample space contains all possible outcomes of the experiment, so some outcome must always occur. An event that is certain to happen has probability 1, and since exactly one outcome in the sample space must occur, P(S) = 1.
The second axiom encodes the idea of certainty. When you run an experiment, something happens — one of the outcomes in S occurs. The probability of 'something happens' must be 1 (certainty). Setting P(S) = 1 ensures the entire probability 'budget' is distributed across outcomes, which in turn means all probabilities must sum to at most 1 and individual probabilities cannot exceed 1.