In mixed-phase clouds (containing both liquid droplets and ice crystals), ice crystals grow rapidly at the expense of liquid droplets because the saturation vapor pressure is lower over ice than over water. This Bergeron process is extremely efficient and is the primary precipitation mechanism in mid-latitude and polar clouds. It explains why ice crystals appearing in supercooled clouds trigger rapid precipitation.
Study the vapor pressure difference between water and ice as a function of temperature; examine mixed-phase cloud radar signatures; observe how seeding clouds with ice nuclei affects precipitation.
From your study of cloud condensation nuclei and latent heat, you know that water vapor in the atmosphere condenses onto tiny particles to form cloud droplets, and that phase changes release or absorb energy. The Bergeron process builds on a subtle but powerful consequence of these ideas: ice and liquid water coexisting in the same cloud creates a vapor pressure imbalance that drives rapid ice crystal growth and is responsible for most precipitation outside the tropics.
The key physical fact is that saturation vapor pressure over ice is lower than over liquid water at the same subfreezing temperature. Imagine a cloud between about −10°C and −20°C containing both supercooled liquid droplets and a few ice crystals. The air may be saturated with respect to liquid water — meaning the droplets are in equilibrium with their surroundings — but that same air is actually supersaturated with respect to the ice surface. Water vapor molecules deposit onto the ice crystals faster than they sublimate away, so the ice crystals grow. As vapor is consumed by the growing crystals, the air dips below liquid saturation, causing the liquid droplets to evaporate to restore equilibrium. The net effect is a transfer of mass from liquid droplets to ice crystals, with the vapor phase acting as an intermediary. The liquid droplets shrink and disappear; the ice crystals fatten.
This process is remarkably efficient. A single ice crystal in a field of supercooled droplets can grow to precipitation size in about 15–20 minutes — far faster than droplets could grow by collision-coalescence alone in such clouds. The resulting ice crystals may aggregate into snowflakes as they fall, or melt into raindrops if they pass through a warm layer below. In mid-latitude weather systems, where cloud tops routinely reach temperatures cold enough for mixed-phase conditions, the Bergeron process is the dominant precipitation mechanism.
Understanding when the Bergeron process is active versus when warm-rain collision-coalescence dominates depends on cloud temperature structure. Tropical maritime clouds with warm bases and tops that barely reach freezing produce rain almost entirely through droplet collisions. Mid-latitude and polar clouds, with extensive subfreezing layers, rely heavily on ice-phase growth. Cloud seeding exploits the Bergeron process directly: introducing artificial ice nuclei (like silver iodide) into a supercooled cloud creates more ice crystals, triggering the vapor pressure imbalance and enhancing precipitation — though only if the cloud already contains sufficient supercooled liquid water for the transfer to occur.