Deductive reasoning formalizes proving conclusions from premises using explicit inference rules. A proof system defines axioms and rules that allow deriving new formulas from given ones. A formula is provable from Γ (Γ ⊢ φ) if there exists a finite derivation sequence using the rules.
Study concrete proof systems and practice constructing proofs. Compare different systems (natural deduction is intuitive; sequent calculus is systematic; resolution is computational). Understand the syntactic/semantic distinction.
Thinking proof systems are purely mechanical. Confusing a proof of φ with proof that φ is true. Assuming different systems prove different theorems (Completeness Theorem shows they do not for first-order logic).
You already understand logical implication: Γ ⊨ φ means every interpretation that satisfies all formulas in Γ also satisfies φ. That is a semantic notion — it talks about truth in models. A proof system introduces a parallel syntactic notion: Γ ⊢ φ means φ can be derived from Γ by applying a finite sequence of explicit rules, without ever asking what is "true." The relationship between ⊨ and ⊢ is the central question of proof theory.
A proof system has two components: axioms (formulas taken as given) and inference rules (patterns like "from formula A and formula A → B, derive B" — this particular rule is called modus ponens). A proof of φ from Γ is a finite sequence of formulas where each step is either an axiom, a member of Γ, or the result of applying an inference rule to earlier steps. The last formula in the sequence is φ. This is entirely syntactic: you can verify a proof by checking, line by line, that each step is licensed — no semantic judgment required.
Different proof systems — natural deduction, sequent calculus, Hilbert-style axiom systems, resolution — differ in how they organize the same logical machinery. Natural deduction mirrors mathematical practice: it has introduction and elimination rules for each connective (∧-introduction, →-elimination = modus ponens, etc.), and proofs look like the reasoning a mathematician actually writes. Sequent calculus uses a different format (Γ ⊢ Δ, asserting that not all of Γ can be true while all of Δ are false) and is more symmetric and algorithmic. Hilbert-style systems push almost everything into axioms and use very few rules. Resolution (your prerequisite for CNF) is designed for automated theorem proving.
The Completeness Theorem for first-order logic states that these systems all prove exactly the same theorems: Γ ⊢ φ if and only if Γ ⊨ φ. Provability and semantic consequence coincide. This is not trivially obvious — it is a deep theorem (proved by Gödel in 1929) that guarantees proof systems are not missing anything. Soundness (⊢ implies ⊨) is the easy direction: if you can prove φ from Γ, then φ really follows from Γ. Completeness (⊨ implies ⊢) is the hard direction: if φ follows semantically, then there is always a formal proof. Together they mean the syntactic game of proof and the semantic game of truth are perfectly matched — for first-order logic. (Gödel's *incompleteness* theorems, which you will encounter later, show arithmetic is a different story.)