An equipotential surface is a set of points at the same potential; no work is required to move a charge along it. Electric field lines are perpendicular to equipotential surfaces and point in direction of decreasing potential.
You already know that electric potential V measures the potential energy per unit charge at a point in space. An equipotential surface is simply a surface where V is constant — like a contour line on a topographic map, but in three dimensions. Moving a charge along an equipotential requires no work, because work = q·ΔV and ΔV = 0 by definition. This is the electric analogue of moving horizontally on a hillside: you neither gain nor lose gravitational potential energy.
The perpendicularity of field lines to equipotential surfaces follows directly from the relationship between E⃗ and V you learned as a prerequisite: E⃗ = −∇V. The electric field points in the direction of steepest descent of potential, which is always perpendicular to surfaces of constant potential — just as a ball rolls straight downhill, not along a contour. If the field had any component parallel to an equipotential, it would mean potential is changing along that surface, which would contradict the surface being equipotential.
The geometry of equipotentials tells you the shape of the field. For an isolated point charge, the equipotentials are concentric spheres and field lines radiate outward — symmetric and easy to visualize. For two equal and opposite charges (a dipole), the equipotentials bulge asymmetrically and field lines curve from the positive to the negative charge. The denser the field lines (or equivalently, the closer the equipotential surfaces are packed), the stronger the field in that region. Near a sharp conductor tip, equipotentials crowd together, which means E⃗ is large — this is why lightning rods and sharp edges can produce high fields and sparking.
Conductors in electrostatic equilibrium offer a powerful application: the entire conductor is an equipotential. Because charges are free to move, any tangential component of E⃗ on the surface would drive current, which contradicts equilibrium. Therefore, E⃗ must be perpendicular to the conductor surface, and the conductor's surface is itself an equipotential. This insight directly enables the analysis of capacitors, shielded regions, and complex conductor geometries — making equipotential surfaces one of the most practical tools in electrostatics.