Aldehydes (C=O at the end of a chain) use the -al suffix; ketones use -one. Carboxylic acids use -oic acid and take priority in numbering. Esters, amides, and acid chlorides use suffixes -oate, -amide, and -oyl chloride, with the parent acid determining the base name.
Name increasingly complex structures with carbonyls and carboxylic acids, paying close attention to functional group priorities and ensuring correct suffix selection.
You already know how to name alkanes using IUPAC rules: find the longest chain, number from one end, and attach the right suffix. Naming carbonyls and carboxylic acids follows the same logic, but with one critical addition — functional group priority determines which suffix wins and which end of the chain gets position 1. The carbonyl group (C=O) is the defining feature of several functional groups, and each one has its own suffix that replaces the -e of the parent alkane name.
Aldehydes have the carbonyl at the end of a chain, so the carbonyl carbon is always carbon 1 — you never need to specify its position. Drop the -e from the parent name and add -al. Methanal (formaldehyde), ethanal (acetaldehyde), and propanal are the simplest examples. Ketones have the carbonyl between two carbons within the chain. Drop the -e and add -one, with a number indicating the carbonyl position: propan-2-one, pentan-3-one. The chain is numbered to give the carbonyl the lowest possible locant.
Carboxylic acids take the highest naming priority among these groups. The suffix is -oic acid, and the carboxyl carbon is always carbon 1. Ethanoic acid (acetic acid) and propanoic acid are straightforward examples. When a carboxylic acid is present alongside a ketone in the same molecule, the acid suffix takes priority and the ketone is indicated with an "oxo-" prefix instead of the -one suffix. This hierarchy — carboxylic acid > aldehyde > ketone — is one of the most frequently tested concepts in organic nomenclature.
The carboxylic acid derivatives follow a consistent pattern based on what replaces the -OH of the acid. Esters use the suffix -oate with the alkyl group from the alcohol named first as a separate word (e.g., methyl ethanoate). Amides replace -oic acid with -amide (ethanamide). Acid chlorides use -oyl chloride (ethanoyl chloride). In each case, the parent chain is named from the carbonyl carbon of the original acid. The key to mastering these names is recognizing that every derivative is named by reference to its parent acid — once you can name the acid, the derivative names follow by swapping suffixes.