Atomic nuclei consist of protons and neutrons (nucleons) bound by the strong nuclear force, which is short-range and much stronger than electrostatic repulsion. The mass of a nucleus is less than the sum of its constituent nucleon masses; the difference, converted via E = Δmc², is the binding energy holding the nucleus together. Binding energy per nucleon peaks near iron (A ≈ 56) and decreases for both lighter and heavier nuclei — this is why energy is released in both fusion (combining light nuclei) and fission (splitting heavy ones).
Calculate the mass defect and binding energy of deuterium and helium-4 numerically. Plot binding energy per nucleon versus mass number to see the iron peak. Discuss the competition between the strong force (attractive, short-range) and Coulomb repulsion (repulsive, long-range).
You have already studied Coulomb's law — the electrostatic repulsion between like charges — and mass-energy equivalence, E = mc². Nuclear structure is where both come into play simultaneously, and understanding it requires holding two competing forces in mind at once. Inside a nucleus, protons are packed into a volume roughly 100,000 times smaller than the atom itself. Coulomb repulsion between them is enormous. The fact that nuclei hold together at all means something must overcome that repulsion — and it does: the strong nuclear force.
The strong nuclear force is short-range (it operates only within about 1–2 femtometers, roughly the size of a nucleon) and is far more powerful than electrostatic repulsion at those distances. It acts attractively between any two nucleons — proton-proton, neutron-neutron, or proton-neutron — regardless of charge. Neutrons contribute to binding without adding to the Coulomb repulsion, which is why heavier stable nuclei have an increasing ratio of neutrons to protons: extra neutrons supply additional strong-force attraction to hold the growing number of protons together. Beyond a certain size, however, even this trick fails — nuclei heavier than lead or bismuth are all unstable to some form of radioactive decay.
When nucleons assemble into a nucleus, the assembled nucleus is measurably lighter than the sum of its constituent masses measured separately. This is the mass defect, Δm. By Einstein's mass-energy equivalence, that missing mass corresponds to energy that was released when the nucleus formed — or equivalently, to the energy you would need to supply to pull the nucleus apart into free nucleons. This energy is the binding energy: BE = Δmc². A nucleus with a large mass defect is tightly bound and takes a lot of energy to disassemble. Binding energy per nucleon (BE divided by A, the mass number) is the most useful measure of nuclear stability — it tells you how tightly each nucleon is held, on average.
Plotting binding energy per nucleon against mass number A reveals a striking shape: it rises steeply for the lightest nuclei, peaks near iron-56 (at about 8.8 MeV per nucleon), and then gradually declines for heavier nuclei. Iron-56 is the most tightly bound nucleus per nucleon. This curve is the key to understanding nuclear energy release. Any nuclear reaction that moves nuclei toward the iron peak releases energy, because the products are more tightly bound than the reactants. Heavy nuclei like uranium are on the right side of the peak — splitting them (fission) produces mid-mass fragments closer to iron, with higher binding energy per nucleon, releasing the difference. Light nuclei like hydrogen and helium are on the left side of the peak — fusing them (fusion) produces heavier nuclei closer to iron, again releasing the difference.
The common misconception is that heavier always means more stable. It does not: stability peaks at iron. Both uranium (too heavy) and hydrogen (too light) are 'climbing toward iron' when they undergo fission and fusion respectively, and it is that climb — the gain in binding energy per nucleon — that powers nuclear reactors and stars. The Sun fuses hydrogen to helium; massive stars eventually reach iron in their cores and stop, because there is no more energy to be gained by nuclear reactions beyond that point.