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Drude and Sommerfeld Models

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The Ideal Fermi Gas: Ground State and ExcitationsBand Theory of SolidsBoltzmann Transport EquationSuperconductivity: Phenomenology (Meissner, London Equations)
drude-model sommerfeld-model free-electron electrical-conductivity

Core Idea

The Drude model treats conduction electrons as a classical ideal gas that undergoes collisions with a characteristic relaxation time tau, yielding the DC conductivity sigma = ne2 tau / m and the Hall coefficient R_H = -1/ne. It correctly predicts Ohm's law and the Wiedemann-Franz ratio but fails for the electronic specific heat (predicting 3/2 k_B per electron, far too large). The Sommerfeld model corrects this by applying Fermi-Dirac statistics: at temperature T, only the fraction ~k_BT/E_F of electrons near the Fermi surface are thermally active, giving a specific heat C_el = (pi2/2)(k_BT/E_F)(Nk_B) that is linear in T and much smaller than the classical prediction.

Explainer

The Drude model (1900) is the simplest theory of electrical conduction: treat the n conduction electrons per unit volume as a classical ideal gas that undergoes random collisions every tau seconds on average, each collision randomizing the electron's velocity. Between collisions, an applied electric field E accelerates each electron, producing a drift velocity v_d = -eE tau/m and a current density j = nev_d = (ne2 tau/m)E. This immediately gives Ohm's law with conductivity sigma = ne2 tau/m. The model also predicts the Hall effect (R_H = -1/ne), AC conductivity (sigma(omega) = sigma_0/(1 - i omega tau)), and a Wiedemann-Franz-like ratio between thermal and electrical conductivity.

The Drude model has two major failures, both rooted in its classical treatment of electron statistics. First, the specific heat: equipartition gives each electron 3k_B/2, predicting a total electronic specific heat of (3/2)nk_B — far larger than what is observed. Experimentally, the electronic specific heat at room temperature is roughly 1% of the classical value. Second, the magnetic susceptibility: classical electrons should exhibit Curie-like paramagnetism proportional to 1/T, but metals show temperature-independent Pauli paramagnetism.

Sommerfeld (1928) resolved both problems by a single change: replacing the Maxwell-Boltzmann distribution with the Fermi-Dirac distribution. At temperature T, the occupation of states follows f(E) = 1/(e(E-E_F)/k_BT + 1). Since E_F is typically 5-10 eV while k_BT at room temperature is only 0.025 eV, the Fermi function is nearly a step function. Only electrons within ~k_BT of E_F can be thermally excited — a fraction k_BT/E_F of the total. This immediately gives a specific heat C_el = gamma T with gamma proportional to g(E_F) (and thus to m*/m), roughly 100 times smaller than the classical prediction at room temperature. Similarly, only Fermi-surface electrons can flip their spin in a magnetic field, giving temperature-independent Pauli paramagnetism chi = mu_B2 g(E_F).

The Sommerfeld model retains the free-electron assumption (no lattice potential, parabolic dispersion) and the phenomenological relaxation time tau. Despite this simplicity, it quantitatively explains the electronic specific heat and magnetic susceptibility of simple metals and provides the correct framework for understanding transport. Its limitations — inability to explain band gaps, the sign of the Hall coefficient in some metals, or the origin of tau itself — are addressed by adding the periodic lattice potential (Bloch's theorem) and the theory of electron-phonon and electron-impurity scattering.

Practice Questions 4 questions

Prerequisite Chain

Understanding ZeroThe Number ZeroCounting to FiveCounting to 10Counting to 20Counting a Set of Objects Up to 20Cardinality: The Last Number CountedMatching Numerals to QuantitiesSubitizing Small QuantitiesAddition Within 10Number Bonds to 10Addition Within 20Doubles and Near DoublesDoubles Facts Within 10Near Doubles Facts Within 20Mental Math Strategies for AdditionMental Math: Adding and Subtracting TensAddition Within 100Repeated Addition as MultiplicationMultiplication as Equal GroupsMultiplication: ArraysBasic Multiplication Facts (0s, 1s, 2s, 5s, 10s)Multiplication Facts Within 100Division as Equal SharingDivision as Grouping (Measurement Division)Division: Grouping (Repeated Subtraction) ModelDivision: Fair Sharing ModelDivision as Equal SharingDivision as GroupingBasic Division FactsDivision Facts Within 100Multiplication and Division Fact FamiliesRelationship Between Multiplication and DivisionDivision Facts as Inverse of MultiplicationRemainders and Quotients in DivisionDivision Word ProblemsMulti-Step Word ProblemsSolving Multi-Step Word ProblemsMultiplication Word ProblemsDivision Word ProblemsIntroduction to Long DivisionFactors and MultiplesPrime and Composite NumbersEquivalent FractionsRelating Fractions and DecimalsDecimal Place ValueIntegers and the Number LineComparing and Ordering IntegersAbsolute ValueAdding IntegersSubtracting IntegersMultiplying IntegersDividing IntegersUnit RatesProportionsPercent ConceptConverting Between Fractions, Decimals, and PercentsOperations with Rational NumbersTwo-Step EquationsSolving Multi-Step EquationsEquations with Variables on Both SidesAngle Pairs: Complementary, Supplementary, and VerticalParallel Lines and TransversalsCorresponding AnglesAlternate Interior AnglesTriangle Angle Sum TheoremExterior Angle TheoremTriangle Inequality TheoremSimilar Triangles: AA SimilaritySimilar Triangles: SSS and SAS SimilarityProportions in Similar TrianglesRight Triangle Trigonometry IntroductionSine, Cosine, and Tangent RatiosTrigonometric Ratios ReviewRadian MeasureConverting Between Degrees and RadiansThe Unit CircleGraphing Sine and CosineGraphing Tangent and Reciprocal Trigonometric FunctionsDerivatives of Trigonometric FunctionsAntiderivativesIndefinite IntegralsBasic Integration RulesRiemann SumsDefinite Integral DefinitionDouble Integrals: Definition and SetupIterated Integrals and Fubini's TheoremDouble Integrals over Rectangular RegionsDouble Integrals over General RegionsApplications of Double Integrals: Area, Mass, and MomentsTriple Integrals in Cartesian CoordinatesTriple Integrals in Cylindrical and Spherical CoordinatesChange of Variables and the Jacobian DeterminantApplications of Triple Integrals: Volume and MassVector Fields and Their RepresentationsLine Integrals of Vector FieldsWork and CirculationLine Integrals of Scalar and Vector FunctionsFundamental Theorem for Line IntegralsConservative Vector FieldsConservative Vector Fields and Potential FunctionsCurl and Divergence of Vector FieldsCurl and DivergenceDivergence TheoremElectric Flux and Divergence TheoremGauss's Law: Integral Form and MeaningSolving Problems with Gauss's LawConductors in Electrostatic EquilibriumCapacitance and CapacitorsDielectricsDielectric Constant and Relative PermittivityElectric Field Inside Dielectric MaterialsDielectric Materials and PolarizationDielectric Susceptibility and PermittivityEnergy Density in Electric FieldsElectric Current and Current DensityElectrical Resistance and ResistivityOhm's Law and Circuit ElementsElectromotive Force (EMF) and BatteriesKirchhoff's Circuit Laws: Voltage and CurrentDC Circuit Network Analysis MethodsTransient Response in RC CircuitsRC CircuitsLC and RLC CircuitsAC Circuits: FundamentalsImpedance and ReactanceAC Power and ResonanceElectromagnetic WavesPostulates of Special RelativityTime DilationLength ContractionLorentz TransformationRelativistic Velocity AdditionRelativistic Momentum and EnergyMass-Energy Equivalence and E=mc²Photons 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