The Ideal Fermi Gas: Ground State and Excitations

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Core Idea

An ideal Fermi gas at T=0 has all states filled up to the Fermi energy E_F, which depends on particle density as E_F ∝ (n)^(2/3). At finite T, excitations near the Fermi surface contribute to heat capacity as C_V ∝ T, much smaller than the classical equipartition value. Pressure and other thermodynamic quantities follow from the density of states.

Explainer

From Fermi-Dirac statistics, you know the average occupation of a single-particle state with energy ε is ⟨n_ε⟩ = 1/(e^{(ε − μ)/kT} + 1). At T = 0, this step function is exactly 1 for ε < μ and exactly 0 for ε > μ. The ideal Fermi gas applies this to N non-interacting fermions confined to a box, asking: what is the ground state, and how does the system behave at low temperature?

At T = 0, the ground state is the Fermi sea: fill every single-particle state in increasing energy order, one fermion per state (respecting the Pauli exclusion principle), until all N fermions are placed. The energy of the last filled state is the Fermi energy, E_F = (ℏ²/2m)(3π²n)^{2/3}, where n = N/V is the number density. For electrons in a typical metal, n ~ 10²⁸ m⁻³, giving E_F ~ 5 eV — equivalent to a temperature of roughly 60,000 K. Even at absolute zero, the electrons have enormous kinetic energy, and the zero-temperature pressure (the degeneracy pressure) does not vanish. This quantum pressure supports white dwarf stars against gravitational collapse.

The low-temperature behavior reveals another dramatic departure from classical intuition. Classically, each gas particle contributes (3/2)k to the heat capacity, giving C_V = (3/2)Nk = (3/2)R per mole. But in a Fermi gas at temperature T, only electrons within approximately kT of the Fermi surface can be thermally excited — those deep in the Fermi sea cannot jump upward because all nearby states are already occupied. The fraction of electrons that participate is roughly kT/E_F, so the heat capacity is reduced by this factor: C_V ≈ (π²/2)(kT/E_F)Nk ∝ T, linear in temperature rather than constant. For typical metals at room temperature, kT/E_F ~ 300 K / 60,000 K ~ 0.005, so the electronic heat capacity is about 200 times smaller than the classical prediction. This explains why the heat capacity of metals is dominated by lattice vibrations (phonons ∝ T³) at low T and rises only weakly, with electronic contributions showing up as the linear term in careful measurements at very low temperatures — a key confirmation that conduction electrons behave as a degenerate Fermi gas.

Practice Questions 5 questions

Prerequisite Chain

Counting to 10Counting to 20Understanding ZeroThe Number ZeroCounting to FiveOne-to-One CorrespondenceCombining Small Groups Within 5Addition Within 10Addition Within 20Two-Digit Addition Without RegroupingTwo-Digit Addition with RegroupingAddition Within 100Repeated Addition as MultiplicationMultiplication Facts Within 100Division as Equal SharingDivision as Grouping (Measurement Division)Division: Grouping (Repeated Subtraction) ModelDivision: Fair Sharing ModelDivision as Equal SharingDivision as GroupingBasic Division FactsDivision Facts Within 100Two-Digit by One-Digit DivisionDivision with RemaindersRemainders and Quotients in DivisionDivision Word ProblemsIntroduction to Long DivisionFactors and MultiplesPrime and Composite NumbersEquivalent FractionsRelating Fractions and DecimalsDecimal Place ValueReading and Writing DecimalsComparing and Ordering DecimalsAdding and Subtracting DecimalsMultiplying DecimalsDividing DecimalsDividing FractionsMixed Number ArithmeticOrder of OperationsInteger Order of OperationsVariable ExpressionsCombining Like TermsOne-Step EquationsTwo-Step EquationsSolving Multi-Step EquationsEquations with Variables on Both SidesAngle Pairs: Complementary, Supplementary, and VerticalParallel Lines and TransversalsCorresponding AnglesAlternate Interior AnglesTriangle Angle Sum TheoremExterior Angle TheoremTriangle Inequality TheoremSimilar Triangles: AA SimilaritySimilar Triangles: SSS and SAS SimilarityProportions in Similar TrianglesRight Triangle Trigonometry IntroductionTrigonometric Ratios ReviewRadian MeasureConverting Between Degrees and RadiansThe Unit CircleGraphing Sine and CosineGraphing Tangent and Reciprocal Trigonometric FunctionsDerivatives of Trigonometric FunctionsAntiderivativesIterated Integrals and Fubini's TheoremDouble Integrals in Cartesian CoordinatesDouble Integrals over Rectangular RegionsDouble Integrals in Polar CoordinatesDouble Integrals: Definition and SetupIterated Integrals and Fubini's TheoremDouble Integrals over Rectangular RegionsDouble Integrals over General RegionsApplications of Double Integrals: Area, Mass, and MomentsTriple Integrals in Cartesian CoordinatesTriple Integrals in Cylindrical and Spherical CoordinatesChange of Variables and the Jacobian DeterminantApplications of Triple Integrals: Volume and MassVector Fields and Their RepresentationsLine Integrals of Vector FieldsGreen's TheoremSurface Integrals and Flux of Vector FieldsSurface Integrals and Flux of Vector FieldsDivergence Theorem: Flux and OutflowDivergence TheoremElectric FluxGauss's LawConductors in Electrostatic EquilibriumCapacitance and CapacitorsDielectricsDielectric Constant and Relative PermittivityElectric Field Inside Dielectric MaterialsDielectric Materials and PolarizationDielectric Susceptibility and PermittivityEnergy Density in Electric FieldsElectric Current and Current DensityElectrical Resistance and ResistivityOhm's Law and Circuit ElementsElectromotive Force (EMF) and BatteriesKirchhoff's Circuit Laws: Voltage and CurrentDC Circuit Network Analysis MethodsTransient Response in RC CircuitsRC CircuitsLC and RLC CircuitsAC Circuits: FundamentalsImpedance and ReactanceAC Power and ResonanceElectromagnetic WavesThe Electromagnetic SpectrumBlackbody Radiation and Planck's LawPhotoelectric EffectThe Photon: Light as QuantaCompton ScatteringWave-Particle Dualityde Broglie WavelengthHeisenberg Uncertainty PrincipleWavefunction and the Born RuleThe Schrödinger EquationState Vectors and WavefunctionsQuantum SuperpositionQuantum EntanglementBell Theorem and Bell InequalitiesPostulates of Quantum MechanicsScattering TheoryIntroduction to Scattering TheoryPartial Wave Analysis in ScatteringSpin Angular MomentumElectron Spin and Intrinsic Magnetic MomentStern-Gerlach Experiment: Spin Quantization and MeasurementElectron Diffraction and Matter Wave PropertiesDavisson-Germer Experiment: Crystal Diffraction of ElectronsElectron Diffraction and Matter Wave InterferenceWavefunctions and Probability Density InterpretationQuantum Superposition and Linear Combinations of StatesQuantum Operators and ObservablesCanonical Commutation Relations and UncertaintyThe Quantum Harmonic OscillatorThe Debye Model of Lattice VibrationsDebye Model of SolidsDebye TemperaturePhonon Statistics and Dispersion RelationsQuantum Statistics: Fermions vs BosonsFermi-Dirac Distribution and Fermi EnergyThe Ideal Fermi Gas: Ground State and Excitations

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