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Hubbard Model

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Tight-Binding ModelFermi Liquid TheoryMott Insulators
hubbard-model electron-correlation mott-transition strongly-correlated

Core Idea

The Hubbard model is the simplest model of interacting electrons on a lattice: H = -t sum_{<ij>,sigma} c^dagger_{i,sigma} c_{j,sigma} + U sum_i n_{i,up} n_{i,down}. The first term is nearest-neighbor hopping (kinetic energy, bandwidth W ~ zt), and the second penalizes double occupancy of any site by Coulomb repulsion U. The competition between kinetic energy (which delocalizes electrons) and interaction energy (which localizes them) produces a rich phase diagram including metallic, Mott insulating, antiferromagnetic, and (in some geometries) superconducting phases. At half-filling with U >> t, the model reduces to the Heisenberg antiferromagnet. The Hubbard model is believed to capture the essential physics of high-temperature superconductivity in the cuprates.

Explainer

The Hubbard model is to strongly correlated electron physics what the Ising model is to statistical mechanics: the simplest possible model that captures the essential competition. It was introduced independently by Hubbard, Gutzwiller, and Kanamori in 1963, and it contains just two parameters. The hopping integral t measures the amplitude for an electron to tunnel between neighboring sites (kinetic energy, favoring delocalization). The on-site repulsion U penalizes having two electrons (with opposite spins) on the same site (interaction energy, favoring localization). The tension between these two tendencies produces the rich physics of correlated electrons.

For U = 0, the Hubbard model is just the tight-binding model — non-interacting electrons forming energy bands. Band theory says a half-filled band is metallic. For U >> t at half-filling, every site is singly occupied and charge fluctuations are frozen out — the system is a Mott insulator with a charge gap of order U. This is the fundamental failure mode of band theory: interactions can make an insulator out of what band theory predicts is a metal. Transition metal oxides like NiO, CoO, and V_2O_3 are Mott insulators, and their insulating behavior puzzled physicists until Mott's insight that Coulomb correlations are responsible.

In the Mott insulating limit (U >> t, half-filling), the remaining degree of freedom is the spin on each site. Virtual hopping processes (electron hops to a neighbor and back, through a high-energy doubly-occupied intermediate state) generate an effective antiferromagnetic exchange J = 4t2/U between neighboring spins. The half-filled Hubbard model at large U thus maps onto the Heisenberg antiferromagnet, explaining why Mott insulators are so often antiferromagnetically ordered. This connection between charge localization and magnetic ordering is one of the central insights of correlated electron physics.

The most exciting and unsolved regime is the doped Mott insulator: start from the half-filled Mott state and remove some electrons (or add some holes). The doped holes can move through the antiferromagnetic background, disrupting the magnetic order. In the 2D Hubbard model on a square lattice, there is strong numerical and analytical evidence that the doped system develops d-wave superconductivity — the same symmetry observed in cuprate high-T_c superconductors (YBa_2Cu_3O_7, La_{2-x}Sr_xCuO_4, etc.). Whether the Hubbard model rigorously supports superconductivity in 2D, and if so with what T_c, remains one of the great open questions. The model also exhibits stripe phases (interleaved charge and spin order), pseudogap behavior, and other phenomena seen in cuprates. Solving the 2D Hubbard model is simultaneously one of the most important and most difficult problems in theoretical physics.

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Prerequisite Chain

Understanding ZeroThe Number ZeroCounting to FiveCounting to 10Counting to 20Counting a Set of Objects Up to 20Cardinality: The Last Number CountedMatching Numerals to QuantitiesSubitizing Small QuantitiesAddition Within 10Number Bonds to 10Addition Within 20Doubles and Near DoublesDoubles Facts Within 10Near Doubles Facts Within 20Mental Math Strategies for AdditionMental Math: Adding and Subtracting TensAddition Within 100Repeated Addition as MultiplicationMultiplication as Equal GroupsMultiplication: ArraysBasic Multiplication Facts (0s, 1s, 2s, 5s, 10s)Multiplication Facts Within 100Division as Equal SharingDivision as Grouping (Measurement Division)Division: Grouping (Repeated Subtraction) ModelDivision: Fair Sharing ModelDivision as Equal SharingDivision as GroupingBasic Division FactsDivision Facts Within 100Multiplication and Division Fact FamiliesRelationship Between Multiplication and DivisionDivision Facts as Inverse of MultiplicationRemainders and Quotients in DivisionDivision Word ProblemsMulti-Step Word ProblemsSolving Multi-Step Word ProblemsMultiplication Word ProblemsDivision Word ProblemsIntroduction to Long DivisionFactors and MultiplesPrime and Composite NumbersEquivalent FractionsRelating Fractions and DecimalsDecimal Place ValueIntegers and the Number LineComparing and Ordering IntegersAbsolute ValueAdding IntegersSubtracting IntegersMultiplying IntegersDividing IntegersUnit RatesProportionsPercent ConceptConverting Between Fractions, Decimals, and PercentsOperations with Rational NumbersTwo-Step EquationsSolving Multi-Step EquationsEquations with Variables on Both SidesAngle Pairs: Complementary, Supplementary, and VerticalParallel Lines and TransversalsCorresponding AnglesAlternate Interior AnglesTriangle Angle Sum TheoremExterior Angle TheoremTriangle Inequality TheoremSimilar Triangles: AA SimilaritySimilar Triangles: SSS and SAS SimilarityProportions in Similar TrianglesRight Triangle Trigonometry IntroductionSine, Cosine, and Tangent RatiosTrigonometric Ratios ReviewRadian MeasureConverting Between Degrees and RadiansThe Unit CircleGraphing Sine and CosineGraphing Tangent and Reciprocal Trigonometric FunctionsDerivatives of Trigonometric FunctionsAntiderivativesIndefinite IntegralsBasic Integration RulesRiemann SumsDefinite Integral DefinitionDouble Integrals: Definition and SetupIterated Integrals and Fubini's TheoremDouble Integrals over Rectangular RegionsDouble Integrals over General RegionsApplications of Double Integrals: Area, Mass, and MomentsTriple Integrals in Cartesian CoordinatesTriple Integrals in Cylindrical and Spherical CoordinatesChange of Variables and the Jacobian DeterminantApplications of Triple Integrals: Volume and MassVector Fields and Their RepresentationsLine Integrals of Vector FieldsWork and CirculationLine Integrals of Scalar and Vector FunctionsFundamental Theorem for Line IntegralsConservative Vector FieldsConservative Vector Fields and Potential FunctionsCurl and Divergence of Vector FieldsCurl and DivergenceDivergence TheoremElectric Flux and Divergence TheoremGauss's Law: Integral Form and MeaningSolving Problems with Gauss's LawConductors in Electrostatic EquilibriumCapacitance and CapacitorsDielectricsDielectric Constant and Relative PermittivityElectric Field Inside Dielectric MaterialsDielectric Materials and PolarizationDielectric Susceptibility and PermittivityEnergy Density in Electric FieldsElectric Current and Current DensityElectrical Resistance and ResistivityOhm's Law and Circuit ElementsElectromotive Force (EMF) and BatteriesKirchhoff's Circuit Laws: Voltage and CurrentDC Circuit Network Analysis MethodsTransient Response in RC CircuitsRC CircuitsLC and RLC CircuitsAC Circuits: FundamentalsImpedance and ReactanceAC Power and ResonanceElectromagnetic WavesPostulates of Special RelativityTime DilationLength ContractionLorentz TransformationRelativistic Velocity AdditionRelativistic Momentum and EnergyMass-Energy Equivalence and E=mc²Photons as Particles with Energy and MomentumPlanck-Einstein Relation: Energy and FrequencyPhotoelectric EffectThe Photon: Light as QuantaCompton ScatteringWave-Particle Dualityde Broglie WavelengthThe Schrödinger EquationState Vectors and WavefunctionsQuantum SuperpositionQuantum EntanglementBell Theorem and Bell InequalitiesPostulates of Quantum MechanicsObservables and Quantum OperatorsCommutators and Commutation RelationsQuantum Angular MomentumQuantum Mechanical Treatment of HydrogenSolving the Schrödinger Equation for Hydrogen AtomQuantum NumbersElectron ConfigurationPeriodic TrendsCovalent BondingElectronegativity and Bond PolarityIonic BondingLewis StructuresVSEPR Theory and Molecular GeometryMolecular Geometry and Electron Pair GeometryMolecular Polarity and Dipole MomentsIntermolecular ForcesStates of Matter and Phase Changes: Melting, Boiling, and SublimationGas Laws and the Ideal Gas EquationGas Stoichiometry and Volume-Volume CalculationsThermochemistry and EnthalpyHeat Capacity and CalorimetryEntropy and Molecular DisorderSpontaneity and ΔGEntropy and Gibbs Free EnergyChemical EquilibriumStatistical Mechanics: Ensembles and the Boltzmann DistributionPartition Function: Definition and PropertiesEinstein Model of SolidsThe Debye Model of Lattice VibrationsDebye Model of SolidsDebye TemperaturePhonon Statistics and Dispersion RelationsQuantum Statistics: Fermions vs BosonsFermi-Dirac Distribution and Fermi EnergyThe Ideal Fermi Gas: Ground State and ExcitationsFermi Liquid TheoryHubbard Model

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