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Hubbard Model

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Tight-Binding ModelFermi Liquid Theory→→Mott Insulators
hubbard-model electron-correlation mott-transition strongly-correlated

Core Idea

The Hubbard model is the simplest model of interacting electrons on a lattice: H = -t sum_{<ij>,sigma} c^dagger_{i,sigma} c_{j,sigma} + U sum_i n_{i,up} n_{i,down}. The first term is nearest-neighbor hopping (kinetic energy, bandwidth W ~ zt), and the second penalizes double occupancy of any site by Coulomb repulsion U. The competition between kinetic energy (which delocalizes electrons) and interaction energy (which localizes them) produces a rich phase diagram including metallic, Mott insulating, antiferromagnetic, and (in some geometries) superconducting phases. At half-filling with U >> t, the model reduces to the Heisenberg antiferromagnet. The Hubbard model is believed to capture the essential physics of high-temperature superconductivity in the cuprates.

Explainer

The Hubbard model is to strongly correlated electron physics what the Ising model is to statistical mechanics: the simplest possible model that captures the essential competition. It was introduced independently by Hubbard, Gutzwiller, and Kanamori in 1963, and it contains just two parameters. The hopping integral t measures the amplitude for an electron to tunnel between neighboring sites (kinetic energy, favoring delocalization). The on-site repulsion U penalizes having two electrons (with opposite spins) on the same site (interaction energy, favoring localization). The tension between these two tendencies produces the rich physics of correlated electrons.

For U = 0, the Hubbard model is just the tight-binding model — non-interacting electrons forming energy bands. Band theory says a half-filled band is metallic. For U >> t at half-filling, every site is singly occupied and charge fluctuations are frozen out — the system is a Mott insulator with a charge gap of order U. This is the fundamental failure mode of band theory: interactions can make an insulator out of what band theory predicts is a metal. Transition metal oxides like NiO, CoO, and V_2O_3 are Mott insulators, and their insulating behavior puzzled physicists until Mott's insight that Coulomb correlations are responsible.

In the Mott insulating limit (U >> t, half-filling), the remaining degree of freedom is the spin on each site. Virtual hopping processes (electron hops to a neighbor and back, through a high-energy doubly-occupied intermediate state) generate an effective antiferromagnetic exchange J = 4t2/U between neighboring spins. The half-filled Hubbard model at large U thus maps onto the Heisenberg antiferromagnet, explaining why Mott insulators are so often antiferromagnetically ordered. This connection between charge localization and magnetic ordering is one of the central insights of correlated electron physics.

The most exciting and unsolved regime is the doped Mott insulator: start from the half-filled Mott state and remove some electrons (or add some holes). The doped holes can move through the antiferromagnetic background, disrupting the magnetic order. In the 2D Hubbard model on a square lattice, there is strong numerical and analytical evidence that the doped system develops d-wave superconductivity — the same symmetry observed in cuprate high-T_c superconductors (YBa_2Cu_3O_7, La_{2-x}Sr_xCuO_4, etc.). Whether the Hubbard model rigorously supports superconductivity in 2D, and if so with what T_c, remains one of the great open questions. The model also exhibits stripe phases (interleaved charge and spin order), pseudogap behavior, and other phenomena seen in cuprates. Solving the 2D Hubbard model is simultaneously one of the most important and most difficult problems in theoretical physics.

Practice Questions 4 questions

Prerequisite Chain

Understanding Zero → The Number Zero → Counting to Five → Counting to 10 → Counting to 20 → Counting a Set of Objects Up to 20 → Cardinality: The Last Number Counted → Matching Numerals to Quantities → Subitizing Small Quantities → Addition Within 10 → Number Bonds to 10 → Addition Within 20 → Doubles and Near Doubles → Doubles Facts Within 10 → Near Doubles Facts Within 20 → Mental Math Strategies for Addition → Mental Math: Adding and Subtracting Tens → Addition Within 100 → Repeated Addition as Multiplication → Multiplication as Equal Groups → Multiplication: Arrays → Basic Multiplication Facts (0s, 1s, 2s, 5s, 10s) → Multiplication Facts Within 100 → Division as Equal Sharing → Division as Grouping (Measurement Division) → Division: Grouping (Repeated Subtraction) Model → Division: Fair Sharing Model → Division as Equal Sharing → Division as Grouping → Basic Division Facts → Division Facts Within 100 → Multiplication and Division Fact Families → Relationship Between Multiplication and Division → Division Facts as Inverse of Multiplication → Remainders and Quotients in Division → Division Word Problems → Multi-Step Word Problems → Solving Multi-Step Word Problems → Multiplication Word Problems → Division Word Problems → Introduction to Long Division → Factors and Multiples → Prime and Composite Numbers → Equivalent Fractions → Relating Fractions and Decimals → Decimal Place Value → Integers and the Number Line → Comparing and Ordering Integers → Absolute Value → Adding Integers → Subtracting Integers → Multiplying Integers → Dividing Integers → Unit Rates → Proportions → Percent Concept → Converting Between Fractions, Decimals, and Percents → Operations with Rational Numbers → Two-Step Equations → Solving Multi-Step Equations → Equations with Variables on Both Sides → Angle Pairs: Complementary, Supplementary, and Vertical → Parallel Lines and Transversals → Corresponding Angles → Alternate Interior Angles → Triangle Angle Sum Theorem → Exterior Angle Theorem → Triangle Inequality Theorem → Similar Triangles: AA Similarity → Similar Triangles: SSS and SAS Similarity → Proportions in Similar Triangles → Right Triangle Trigonometry Introduction → Sine, Cosine, and Tangent Ratios → Trigonometric Ratios Review → Radian Measure → Converting Between Degrees and Radians → The Unit Circle → Graphing Sine and Cosine → Graphing Tangent and Reciprocal Trigonometric Functions → Derivatives of Trigonometric Functions → Antiderivatives → Indefinite Integrals → Basic Integration Rules → Riemann Sums → Definite Integral Definition → Double Integrals: Definition and Setup → Iterated Integrals and Fubini's Theorem → Double Integrals over Rectangular Regions → Double Integrals over General Regions → Applications of Double Integrals: Area, Mass, and Moments → Triple Integrals in Cartesian Coordinates → Triple Integrals in Cylindrical and Spherical Coordinates → Change of Variables and the Jacobian Determinant → Applications of Triple Integrals: Volume and Mass → Vector Fields and Their Representations → Line Integrals of Vector Fields → Work and Circulation → Line Integrals of Scalar and Vector Functions → Fundamental Theorem for Line Integrals → Conservative Vector Fields → Conservative Vector Fields and Potential Functions → Curl and Divergence of Vector Fields → Curl and Divergence → Divergence Theorem → Electric Flux and Divergence Theorem → Gauss's Law: Integral Form and Meaning → Solving Problems with Gauss's Law → Conductors in Electrostatic Equilibrium → Capacitance and Capacitors → Dielectrics → Dielectric Constant and Relative Permittivity → Electric Field Inside Dielectric Materials → Dielectric Materials and Polarization → Dielectric Susceptibility and Permittivity → Energy Density in Electric Fields → Electric Current and Current Density → Electrical Resistance and Resistivity → Ohm's Law and Circuit Elements → Electromotive Force (EMF) and Batteries → Kirchhoff's Circuit Laws: Voltage and Current → DC Circuit Network Analysis Methods → Transient Response in RC Circuits → RC Circuits → LC and RLC Circuits → AC Circuits: Fundamentals → Impedance and Reactance → AC Power and Resonance → Electromagnetic Waves → Postulates of Special Relativity → Time Dilation → Length Contraction → Lorentz Transformation → Relativistic Velocity Addition → Relativistic Momentum and Energy → Mass-Energy Equivalence and E=mc² → Photons as Particles with Energy and Momentum → Planck-Einstein Relation: Energy and Frequency → Photoelectric Effect → The Photon: Light as Quanta → Compton Scattering → Wave-Particle Duality → de Broglie Wavelength → The Schrödinger Equation → State Vectors and Wavefunctions → Quantum Superposition → Quantum Entanglement → Bell Theorem and Bell Inequalities → Postulates of Quantum Mechanics → Observables and Quantum Operators → Commutators and Commutation Relations → Quantum Angular Momentum → Quantum Mechanical Treatment of Hydrogen → Solving the Schrödinger Equation for Hydrogen Atom → Quantum Numbers → Electron Configuration → Periodic Trends → Covalent Bonding → Electronegativity and Bond Polarity → Ionic Bonding → Lewis Structures → VSEPR Theory and Molecular Geometry → Molecular Geometry and Electron Pair Geometry → Molecular Polarity and Dipole Moments → Intermolecular Forces → States of Matter and Phase Changes: Melting, Boiling, and Sublimation → Gas Laws and the Ideal Gas Equation → Gas Stoichiometry and Volume-Volume Calculations → Thermochemistry and Enthalpy → Heat Capacity and Calorimetry → Entropy and Molecular Disorder → Spontaneity and ΔG → Entropy and Gibbs Free Energy → Chemical Equilibrium → Statistical Mechanics: Ensembles and the Boltzmann Distribution → Partition Function: Definition and Properties → Einstein Model of Solids → The Debye Model of Lattice Vibrations → Debye Model of Solids → Debye Temperature → Phonon Statistics and Dispersion Relations → Quantum Statistics: Fermions vs Bosons → Fermi-Dirac Distribution and Fermi Energy → The Ideal Fermi Gas: Ground State and Excitations → Fermi Liquid Theory → Hubbard Model

Longest path: 185 steps · 1141 total prerequisite topics

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